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In the heart of Serbia, near Kostolac, archaeologists uncovered the remains of an ancient Roman amphitheater: Viminacium. The arena walls, once covered in vivid paintings, tell stories of shows, battles, and myths. To discover which pigments Roman artisans used, researchers combined several techniques: chemical analysis with EDXRF, X-ray powder diffraction (XRD), and Raman and FTIR spectroscopy.

The findings are striking: besides the classic earth tones—yellow, red, brown, and green—more precious pigments emerged. Egyptian blue, made from copper, and lapis lazuli, a semi‑precious stone likely from Afghanistan, show that Romans imported materials from far away to make their scenery spectacular. Cinnabar, an intense mercury‑based red, was also identified, confirming the use of costly colors.

Analyses suggest some pigments came from marine sediments, while others originated from rocks of different regions, indicating an extensive trade network. This not only enriches our knowledge of Roman artistic techniques but also helps reconstruct the role of amphitheaters in provincial Danubian life. In short, Viminacium's painted walls reveal how art, science, and commerce intertwined to create unforgettable spectacles.

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The spectroscopic analyses allowed identification of the characteristic molecular vibrations of each pigment. Raman revealed peaks at 150 cm⁻¹ and 430 cm⁻¹ typical of lapis lazuli, confirming the presence of lazurite, a mineral composed of sodium, aluminum, silica, and sulfur. FTIR showed absorption bands around 1400 cm⁻¹, typical of carbonates present in calcite-based binders. EDXRF quantified metallic elements: high Cu levels indicate copper‑based paint for Egyptian blue, while Hg presence suggests the use of cinnabar, a very expensive red pigment for the period. X‑ray diffraction (XRD) confirmed the crystallinity of the compounds, distinguishing the monoclinic structure of cinnabar (HgS) from the hexagonal structure of lapis lazuli. The material origins were hypothesized by comparing isotopic traces with reference samples: marine sediments rich in phosphates could derive from Adriatic coasts, while lapis‑bearing rocks are typical of Badakhshan mines. These evidences suggest Viminacium was part of a trade network linking the Roman Empire to maritime and overland routes, granting access to high‑quality pigments for public décor. The use of such colors was not merely aesthetic: Egyptian blue, for instance, was associated with marine deities and imperial power, while lapis lazuli symbolized wealth and prestige. This multidisciplinary study shows how chemistry, mineralogy, and archaeology can collaborate to reconstruct not only material composition but also the cultural context of ancient entertainment venues.

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Authors:
Dragana GavrilovićIvan BogdanovićVelibor AndrićMaja Gajić-Kvaščev
Date Published:
Original Article www.mdpi.com
Fact-check verified on 27/05/2026
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Creative Commons License CC BY-NC-SA 4.0

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