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Imagine holding a 19th-century Japanese print: vivid colors, a background shimmering like silver. For centuries that sparkle was a mystery, but physics now has the answer. At the Museo delle Culture in Lugano, ten precious ukiyo-e were "scanned" without contact, using infrared and ultraviolet light. It's like an X-ray for art: no needles, no sampling, just light.

The results dive into traditional chemistry. Pigments come from nature: akane (madder) for reds, suo (sappanwood) for purples, kariyasu (a grass) for yellows, and kio (orpiment) for oranges, all bound with animal glue. The star is bero-ai, Prussian blue: imported from Europe, it won over Japanese artists for its intensity and low cost, used pure or mixed for greens and purples.

The real discovery? Mica. Found in the background of one print, it is the first scientific proof of the *kirazuri* technique: mica powder sprinkled on wet paper to mimic the glitter of precious metals or snow. UV light then revealed old water damage and faded motifs, invisible maps to restore the past. Technology doesn't destroy the magic; it explains it.

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The investigation, published in *Heritage*, employed external reflection infrared spectroscopy (ER-FTIR) and hyperspectral imaging to overcome the limits of invasive analysis. ER-FTIR allows molecular identification of organic binders (animal glue proteins) and inorganic/organic pigments directly on the verso and recto. The identification of mica (likely muscovite) analytically confirms *kirazuri* ("glitter printing\)), a decorative technique known only from historical sources and visual observation, used for *mica-bokashi* (mica gradation) effects.

The pervasiveness of Prussian blue (ferric ferrocyanide, Fe4[Fe(CN)6]3) marks a technological shift in the late Edo period (post-1829), partially replacing indigo and dayflower blue (ai) for stability and cost. UV fluorescence imaging (UVF) mapped photo-oxidative degradation of organic colorants (plant-based yellows/reds) and orpiment (As2S3) oxidation to arsenolite, alongside water stains (tideline) and past interventions. This non-invasive multimodal approach defines a standard protocol for diagnostics on Japanese paper, supporting conservation decisions based on objective physicochemical evidence.

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Authors:
Laura RampazziValentina BrunelloFrancesco Paolo CampioneCristina CortiLudovico GeminianiSandro RecchiaMoira Luraschi
Date Published:
Original Article www.mdpi.com
Fact-check verified on 26/07/2026
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Creative Commons License CC BY-NC-SA 4.0

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