Mines generate massive amounts of waste, called tailings, that take up space and pollute. A smart fix is turning them into cemented paste backfill (CPB), a material used to fill underground voids. Traditionally, CPB contains Ordinary Portland Cement (OPC), but its production is energy‑intensive and pricey. In a Spanish study, researchers tested three alkaline alternatives to cement: sodium hydroxide (NaOH), sodium silicate (Na₂SiO₃) and a calcined magnesite residue rich in MgCO₃ and MgO. They assessed both mechanical strength and environmental impact using a cradle‑to‑grave life‑cycle analysis (LCA). The findings show that the magnesite‑based mix matches OPC’s compressive strength while dramatically cutting CO₂ emissions and production costs. In practice, this yields a greener material that recycles mining waste and reduces reliance on traditional cement. The approach could transform waste management in mining, making the sector more eco‑friendly and competitive.
The life‑cycle assessment (LCA) followed ISO 14040 standards, covering raw material extraction, binder production, transport, mixing and CPB placement. The calcined magnesite residue, derived from magnesite rich in MgCO₃ and MgO, acts as a magnesium hydroxide precursor in an alkaline environment, promoting the formation of magnesium‑silicate hydrate (M‑S‑H) gels. These gels give the CPB a dense, strong microstructure comparable to the C‑S‑H of Portland cement. Thermodynamically, activation requires less energy than OPC production, as magnesite calcination occurs at lower temperatures (≈ 800 °C) versus clinker (≈ 1450 °C). CO₂ emissions drop due to lower energy use and the absence of calcium carbonate in the binding phase. Economic analysis accounted for residue purchase, logistics and operational costs, revealing an average 30 % savings versus OPC. Finally, durability tests under load‑unload cycles showed chemical resistance similar to traditional CPB, confirming suitability for long‑term underground applications.
