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In 2019 the regional museum of Cáceres, Spain, was offered a head‑shaped pendant claimed to be Phoenician‑Punic, allegedly found near the city. Before buying it, experts had to determine whether it was truly ancient or a modern replica.

Traditional analyses – typology and manufacturing techniques – already raised doubts: the design didn’t match typical Iron Age examples. To go further, researchers used VP‑SEM‑EDS, an electron microscope that reads the glass’s chemical composition without touching the object.

The results revealed elements and pigments typical of glasses produced in recent decades, such as lead and tin oxides, absent from ancient Mediterranean recipes. By comparing these data with historical and modern recipes, it became clear the pendant was made from contemporary glass, colored and opacified with current techniques.

This finding shows how crucial it is to test objects before museums acquire them: non‑invasive technologies can expose fakes that would otherwise fool even the most careful experts. Moreover, involving the local community in reporting finds can help protect heritage, but it always requires rigorous scientific verification.

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The VP‑SEM‑EDS (Variable Pressure Scanning Electron Microscopy with Energy Dispersive Spectroscopy) technique provides high‑resolution elemental spectra on non‑conductive samples like ancient glass without the need for metallic coatings. In this case, the scan revealed peaks of lead (Pb) and tin (Sn) associated with modern opacifying pigments, typically used to achieve intense green and blue hues in 20th‑century glass. Moreover, the presence of sodium (Na) and calcium (Ca) in ratios incompatible with Phoenician recipes— which favored silica, soda, and lime in tighter proportions— further refuted an Iron Age attribution.

Reconstructed Phoenician glass recipes, derived from authentic artifacts, show the use of quartz sand, soda, and lime, with occasional antimony or copper for limited coloration. Modern glasses, by contrast, employ lead oxides to increase density and brilliance, and tin compounds to stabilize hues. Lead isotopic analysis, when available, can also distinguish ancient geological sources from modern ones, as Pb‑206/Pb‑207 profiles differ markedly.

A further verification step involves micro‑Raman or FTIR to identify molecular bonds of organic dyes, often absent in ancient glass. Integrating these non‑destructive methods yields a chemical "identity card" of the object, allowing comparison with databases of archaeological and industrial glasses. This multidisciplinary approach is now the standard for assessing glass artifact authenticity, reducing the risk of acquiring forgeries and safeguarding cultural heritage with scientific rigor.

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Authors:
Valentina LončarićPedro BarrulasJosé Miguel González BornayMafalda Costa
Date Published:
Original Article www.mdpi.com
Fact-check verified on 17/01/2026
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Creative Commons License CC BY-NC-SA 4.0

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